UV光(guang)解是繼固態(tai)、液態(tai)、氣態(tai)之后的(de)(de)物質第四態(tai),當外加(jia)電壓達到氣體(ti)(ti)的(de)(de)著火(huo)電壓時(shi),氣體(ti)(ti)分子(zi)被(bei)擊穿(chuan),產生包括電子(zi)、各種離(li)(li)子(zi)、原子(zi)和自(zi)由基在內(nei)的(de)(de)混合體(ti)(ti)。低(di)溫(wen)(wen)(wen)等(deng)(deng)離(li)(li)子(zi)體(ti)(ti)放電過程中雖然(ran)電子(zi)溫(wen)(wen)(wen)度(du)很(hen)高(gao),但重粒子(zi)溫(wen)(wen)(wen)度(du)很(hen)低(di),整個體(ti)(ti)系呈現低(di)溫(wen)(wen)(wen)狀態(tai),所以稱為低(di)溫(wen)(wen)(wen)等(deng)(deng)離(li)(li)子(zi)體(ti)(ti),也叫非(fei)平衡態(tai)等(deng)(deng)離(li)(li)子(zi)體(ti)(ti)。
如果電子(zi)(zi)(zi)的(de)溫度和(he)重(zhong)粒子(zi)(zi)(zi)溫度差不多,則為高溫等離(li)子(zi)(zi)(zi)體,或平(ping)衡態等離(li)子(zi)(zi)(zi)體。
低(di)溫(wen)等(deng)離子(zi)(zi)(zi)(zi)(zi)(zi)(zi)體(ti)中(zhong)能(neng)量(liang)的(de)(de)(de)(de)傳(chuan)遞(di)大致為(wei):電(dian)子(zi)(zi)(zi)(zi)(zi)(zi)(zi)從電(dian)場中(zhong)得到(dao)能(neng)量(liang),通(tong)過(guo)碰撞(zhuang)將能(neng)量(liang)轉化(hua)為(wei)分子(zi)(zi)(zi)(zi)(zi)(zi)(zi)的(de)(de)(de)(de)內能(neng)和動能(neng),獲得能(neng)量(liang)的(de)(de)(de)(de)分子(zi)(zi)(zi)(zi)(zi)(zi)(zi)被(bei)激發,與此同時,部分分子(zi)(zi)(zi)(zi)(zi)(zi)(zi)被(bei)電(dian)離,這(zhe)些活(huo)化(hua)了的(de)(de)(de)(de)粒子(zi)(zi)(zi)(zi)(zi)(zi)(zi)相互碰撞(zhuang)從而(er)引(yin)起一(yi)系列復雜(za)的(de)(de)(de)(de)物(wu)(wu)(wu)理(li)(li)化(hua)學反應(ying)。因等(deng)離子(zi)(zi)(zi)(zi)(zi)(zi)(zi)體(ti)內富含的(de)(de)(de)(de)大量(liang)活(huo)性粒子(zi)(zi)(zi)(zi)(zi)(zi)(zi)如離子(zi)(zi)(zi)(zi)(zi)(zi)(zi)、電(dian)子(zi)(zi)(zi)(zi)(zi)(zi)(zi)、激發態的(de)(de)(de)(de)原子(zi)(zi)(zi)(zi)(zi)(zi)(zi)和分子(zi)(zi)(zi)(zi)(zi)(zi)(zi)及自由(you)基等(deng),從而(er)為(wei)等(deng)離子(zi)(zi)(zi)(zi)(zi)(zi)(zi)體(ti)技(ji)術通(tong)過(guo)化(hua)學反應(ying)處理(li)(li)異(yi)味物(wu)(wu)(wu)質提供了條(tiao)件。它是(shi)基于放電(dian)物(wu)(wu)(wu)理(li)(li)、放電(dian)化(hua)學、反應(ying)工程學的(de)(de)(de)(de)學科(ke)之上(shang)的(de)(de)(de)(de)交叉(cha)學科(ke)。近幾十年來(lai),有關(guan)等(deng)離子(zi)(zi)(zi)(zi)(zi)(zi)(zi)體(ti)技(ji)術的(de)(de)(de)(de)研究非常活(huo)躍(yue),為(wei)合成新(xin)物(wu)(wu)(wu)質、新(xin)材料及環境污(wu)染(ran)治理(li)(li)等(deng)提供了一(yi)種新(xin)技(ji)術、新(xin)方法和新(xin)工藝。低(di)溫(wen)等(deng)離子(zi)(zi)(zi)(zi)(zi)(zi)(zi)體(ti)降解污(wu)染(ran)物(wu)(wu)(wu)是(shi)利用(yong)這(zhe)些高(gao)能(neng)電(dian)子(zi)(zi)(zi)(zi)(zi)(zi)(zi)、自由(you)基等(deng)活(huo)性粒子(zi)(zi)(zi)(zi)(zi)(zi)(zi)和廢氣中(zhong)的(de)(de)(de)(de)污(wu)染(ran)物(wu)(wu)(wu)作用(yong),使污(wu)染(ran)物(wu)(wu)(wu)分子(zi)(zi)(zi)(zi)(zi)(zi)(zi)在短的(de)(de)(de)(de)時間(jian)內發生(sheng)分解,并發生(sheng)后續的(de)(de)(de)(de)各種反應(ying)以達(da)到(dao)降解污(wu)染(ran)物(wu)(wu)(wu)的(de)(de)(de)(de)目的(de)(de)(de)(de)。但(dan)是(shi),無論(lun)是(shi)哪一(yi)種高(gao)壓(ya)(ya)放電(dian)技(ji)術,都(dou)是(shi)通(tong)過(guo)高(gao)壓(ya)(ya)放電(dian)的(de)(de)(de)(de)原理(li)(li),充分考慮(lv)到(dao)爆炸問(wen)題(ti),特別(bie)是(shi)在易(yi)燃易(yi)爆的(de)(de)(de)(de)化(hua)工場合。
冰升溫至0℃會(hui)變成(cheng)水,如繼(ji)續(xu)使溫度(du)升至100℃,那么(me)水就(jiu)(jiu)會(hui)沸騰成(cheng)為水蒸氣。隨著溫度(du)的(de)上升,物(wu)(wu)(wu)質(zhi)(zhi)的(de)存(cun)(cun)在(zai)狀(zhuang)態(tai)(tai)(tai)一(yi)般會(hui)呈現出固(gu)態(tai)(tai)(tai)→液態(tai)(tai)(tai)→氣態(tai)(tai)(tai)三(san)種(zhong)(zhong)物(wu)(wu)(wu)態(tai)(tai)(tai)的(de)轉化過(guo)程(cheng),我(wo)們把(ba)這(zhe)三(san)種(zhong)(zhong)基(ji)本形(xing)態(tai)(tai)(tai)稱為物(wu)(wu)(wu)質(zhi)(zhi)的(de)三(san)態(tai)(tai)(tai)。那么(me)對于(yu)氣態(tai)(tai)(tai)物(wu)(wu)(wu)質(zhi)(zhi),溫度(du)升至幾千度(du)時,將會(hui)有什么(me)新變化呢? 由于(yu)物(wu)(wu)(wu)質(zhi)(zhi)分子(zi)熱(re)運動(dong)加(jia)劇,相互(hu)間(jian)的(de)碰撞就(jiu)(jiu)會(hui)使氣體分子(zi)產生電(dian)(dian)離(li),這(zhe)樣物(wu)(wu)(wu)質(zhi)(zhi)就(jiu)(jiu)變成(cheng)由自由運動(dong)并相互(hu)作用的(de)正(zheng)離(li)子(zi)和電(dian)(dian)子(zi)組成(cheng)的(de)混合物(wu)(wu)(wu)(蠟燭的(de)火(huo)焰就(jiu)(jiu)處于(yu)這(zhe)種(zhong)(zhong)狀(zhuang)態(tai)(tai)(tai))。我(wo)們把(ba)物(wu)(wu)(wu)質(zhi)(zhi)的(de)這(zhe)種(zhong)(zhong)存(cun)(cun)在(zai)狀(zhuang)態(tai)(tai)(tai)稱為物(wu)(wu)(wu)質(zhi)(zhi)的(de)第四態(tai)(tai)(tai),即等(deng)離(li)子(zi)體(plasma)。因為電(dian)(dian)離(li)過(guo)程(cheng)中(zhong)(zhong)正(zheng)離(li)子(zi)和電(dian)(dian)子(zi)總(zong)是(shi)成(cheng)對出現,所以等(deng)離(li)子(zi)體中(zhong)(zhong)正(zheng)離(li)子(zi)和電(dian)(dian)子(zi)的(de)總(zong)數大(da)(da)致(zhi)相等(deng),總(zong)體來看(kan)為準電(dian)(dian)中(zhong)(zhong)性。反過(guo)來,我(wo)們可(ke)以把(ba)等(deng)離(li)子(zi)體定義為:正(zheng)離(li)子(zi)和電(dian)(dian)子(zi)的(de)密度(du)大(da)(da)致(zhi)相等(deng)的(de)電(dian)(dian)離(li)氣體。
產(chan)生方法:
輝(hui)光(guang)(guang)放(fang)(fang)電(dian),電(dian)暈(yun)放(fang)(fang)電(dian),介(jie)質阻擋放(fang)(fang)電(dian),射頻放(fang)(fang)電(dian),滑動(dong)電(dian)弧放(fang)(fang)電(dian),射流放(fang)(fang)電(dian),大氣壓(ya)輝(hui)光(guang)(guang)放(fang)(fang)電(dian),次大氣壓(ya)輝(hui)光(guang)(guang)放(fang)(fang)電(dian)
輝(hui)光放(fang)(fang)電(dian)(dian)屬(shu)于(yu)低(di)氣壓(ya)(ya)(ya)放(fang)(fang)電(dian)(dian)(low pressure discharge),工(gong)作壓(ya)(ya)(ya)力一般都低(di)于(yu)10mbar,其(qi)構造(zao)是(shi)(shi)在封閉的(de)容器內放(fang)(fang)置兩個平行的(de)電(dian)(dian)板,利(li)用電(dian)(dian)子(zi)將中性原子(zi)和分子(zi)激發(fa),當(dang)粒子(zi)由激發(fa)態(excited state)降(jiang)回至基(ji)態(ground state)時會以光的(de)形式(shi)釋放(fang)(fang)出能量。電(dian)(dian)源(yuan)可以為(wei)直流電(dian)(dian)源(yuan)也可以是(shi)(shi)交流電(dian)(dian)源(yuan)。每種氣體都有其(qi)典型的(de)輝(hui)光放(fang)(fang)電(dian)(dian)顏色(如下表(biao)所示),熒(ying)光燈的(de)發(fa)光即為(wei)輝(hui)光放(fang)(fang)電(dian)(dian)。因此(ci),實(shi)(shi)驗時若發(fa)現等(deng)離(li)子(zi)的(de)顏色有誤,通(tong)常代表(biao)氣體的(de)純(chun)度有問題,一般為(wei)漏氣所至。輝(hui)光放(fang)(fang)電(dian)(dian)是(shi)(shi)化學等(deng)離(li)子(zi)體實(shi)(shi)驗的(de)重要工(gong)具,但因其(qi)受低(di)氣壓(ya)(ya)(ya)的(de)限(xian)(xian)制,工(gong)業應(ying)(ying)(ying)用難(nan)于(yu)連(lian)續化生產(chan)且應(ying)(ying)(ying)用成本(ben)高昂,而無法廣泛應(ying)(ying)(ying)用于(yu)工(gong)業制造(zao)中。到2013年止的(de)應(ying)(ying)(ying)用范圍僅局(ju)限(xian)(xian)于(yu)實(shi)(shi)驗室、燈光照(zhao)明產(chan)品(pin)和半導體工(gong)業等(deng)[1] 。